What is SecurityModeCommand in LTE?

It is the downlink LTE RRC message the eNodeB sends to activate access-stratum security for the UE.

What comes after SecurityModeCommand?

The UE responds with SecurityModeComplete if activation succeeds or SecurityModeFailure if it cannot continue.

What should I inspect first in SecurityModeCommand?

Start with the selected ciphering and integrity algorithms in the security configuration.

Why is SecurityModeCommand important in troubleshooting?

It is the step that activates protected LTE RRC signaling, so later dedicated failures often need to be checked back against this point.